New Synthesis of tert-Butyl Peroxycarboxylates
β Scribed by V. A. Donchak; S. A. Voronov; R. S. Yur'ev
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 15 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract Enantiomerically pure benzyl sulfoxides are effective tools for the formation of new CβC bonds with control of configuration at new stereogenic centres. The reaction of enantioenriched __tert__βbutyl __tert__βbutanethiosulfinate with benzyllithium derivatives, obtained by deprotonation
Cyclohexanone monooxygenase from Acinetobacter calcoaceticus catalyzes the asymmetric oxidation of tert-butyl disulfide to enantiomerically pure (R)-tert-butyl tert-butanethiosulfinate. Lower enantioselectivities and conversions were observed in the oxidation of i-propyl, n-butyl, p-tolyl tert-butyl