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New synthesis of pentacyclic steroids by stereoselective epoxide ring opening

✍ Scribed by Malika Ibrahim-Ouali; Hamze Khalil

Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
789 KB
Volume
51
Category
Article
ISSN
0040-4039

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## Abstract A variety of hydroxy epoxides have been obtained from well defined hydroxy‐alkenyl derivatives. Their subsequent intramolecular ring‐opening allowed unprecedented classes of spiro‐lactams to be obtained. The effect of the epoxide stereochemistry and of the reaction temperature on the re