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New synthesis of methano-bridged annulenes: access to highly substituted derivatives

✍ Scribed by Barrett, David G.; Liang, Gui Bai; Gellman, Samuel H.

Book ID
127294728
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
286 KB
Volume
114
Category
Article
ISSN
0002-7863

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## Abstract The novel propellane 3 containing an electron‐rich cyclohexadiene and an electron‐deficient diazadiene system in one and the same molecule reacts site selectively with the electron‐rich alkynes 4 and 8 as well as with cyclooctyne (10) to yield the interestingly substituted novel 1,6‐met