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New synthesis of (E)-3,7-dimethyl-2,7-octadienylpropionate and (E)-3,7-dimethyl-2-octen-1,8-diol, pheromone components of San Jose scaleinsectQuadraspidiotus perniciousand african monarch butterflyDanaus chrysippus

โœ Scribed by G. L. Kad; Sangita Nohria


Book ID
112906865
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
1989
Tongue
English
Weight
223 KB
Volume
101
Category
Article
ISSN
0253-4134

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A novel synthesis of (E)-3,7-dimethyl-2-
โœ Tamotsu Fujisawa; Toshio Sato; Tatsuo Kawara; Atsunari Noda ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 131 KB

The regiosetective ring-opening reaction of a-methyl-B-propiolactone with 3,3-ethytenedioxybutytmagnesiwn bromide in the presence of copper(I) cataZyst afforded 2-methyl-6-oxoheptanoic acid, which was easily converted into IEI-3,7-dimethyl-2-octene-I,&dial in good yield.