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New synthesis of benzo [a]quinolizidin-2-ones via protected 2-aryl-4-piperidones

✍ Scribed by Maria Rubiralta; Anna Diez; Antonia Balet; Joan Bosch

Book ID
108371611
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
912 KB
Volume
43
Category
Article
ISSN
0040-4020

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Synthetic applications of 2-aryl-4-piper
Synthetic applications of 2-aryl-4-piperidones. VIII. Synthesis of methyl indolo[2,3-a]quinolizidin-2-acetate
✍ Mario Rubiralta; Anna Diez; Cristina Vila; Jean-Luc Bettiol; Yves Troin; Marie-E πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 French βš– 238 KB

The synthesis of methyl indolo[2,3-a]quinolizidin-2-acetate (21) from lhydroxyethyl-2-[l -(phenylsulfony/)-3-indolyl]piperidine-4-acetate ( 16) by an intramolecular cyclization induced by KrBuO is described.