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New synthesis of 2,2-dimethyl-3-isopropylidene-cyclopropyl propionate

✍ Scribed by Wakabayashi, Nobel

Book ID
127372409
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
258 KB
Volume
32
Category
Article
ISSN
0022-3263

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New conformationally restricted glutamate analogues 2-(3'-alkyl-2'-carboxycyclopropyl)glycines (la-e and 2a-e) were enantioselectively prepared by the addition-elimination reaction of the chiral lithium bislactim ether anion of 3 to racemic 4-alkyl-4-bromobut-2-enoates.