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New syntheses by amino radicals and oxygen. Conversion of olefins into α-aminoketones.

✍ Scribed by Francesco Minisci; Remo Galli


Publisher
Elsevier Science
Year
1964
Tongue
French
Weight
164 KB
Volume
5
Category
Article
ISSN
0040-4039

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📜 SIMILAR VOLUMES


Simple syntheses of hydroxamic acids and
✍ Saı̈d Boukhris; Abdelaziz Souizi 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 168 KB

The nucleophilic ring opening of gem-dicyanoepoxides by LiBr or Li 2 NiBr 4 , in the presence of hydroxylamine derivatives leads to new α-halo hydroxamic acids. These compounds has been used in the synthesis of αfunctionalized hydroxamic acids, α-hydroxy and α-amino acids in good yields.