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New stereoselective method for the preparation of vicinal diamines from olefins and cyanamide

โœ Scribed by Kohn, Harold; Jung, Sang Hun

Book ID
120087943
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
373 KB
Volume
105
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

A new method for the preparation of olef
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A novel method is reported for the transformation of vicinal diols to olefins. This methodology consists in the conversion of iodothiocarbonates such as 16 to olefin 17 with phenyl lithium in excellent yield. Compounds 7 and 12 were prepared by this methodology in order to determine if they would be

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sumnary: Selective reductive procedures for the preparation of vicinal diamines and rrpncmines fran alkyl bromxyanamides are described. The frequent occurrence of the vicinal diamine functionality (1, in important naturally occurring compounds and medicinal agents renders this group a worthy synthe