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New split injection technique in capillary column gas chromatography

โœ Scribed by Ernst Bayer; G.H. Liu


Book ID
108336864
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
917 KB
Volume
256
Category
Article
ISSN
1873-3778

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The effect of sample injection temperature on quantitation is examined for on-column and conventional split modes of sampling in capillary gas chromatography. Discrimination effects can be observed even with on-column injection if the injection temperature is too far above the boiling point of the s

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## Abstract Discrimination may occur when injecting samples onto gas chromatography capillary columns, whereby peak areas for higher boiling point compounds are smaller than they should be compared to lower boiling compounds. This problem is most important in quantitative work on solutes having a w