New Routes to η 1 - and (η 3 ↔η 5 )-Indenylpalladium Complexes: Synthesis, Characterization, and Reactivities
✍ Scribed by Sui-Seng, Christine; Enright, Gary D.; Zargarian, Davit
- Book ID
- 120823856
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 228 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0276-7333
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η 3 ,η 1 -diyl hafnium complexes / 1,3,5-Triphosphabicyclo[3.1.0]hexene / 1,3,5-Triphosphacyclohexa-1,4-diene / Cyclotrimerization / Phosphaalkyne It is shown that the (PϵC-tBu) 3 ligand found in the hafnium 31 P-NMR spectra with those of the complexes 12 and 14. The organophosphorus ligand in all t
## Abstract The synthesis of the first example of a complex in which methylphosphaalkyne solely η^1^‐coordinates a metal center, [RuH(dppe)~2~(η^1^‐P≡CMe)][CF~3~SO~3~] [dppe = 1,2‐bis(diphenylphosphanyl)ethane], is reported. Treatment of this compound with HBF~4~ (acting as a source of HF) has led