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New routes to carbene complexes for thermally and oxidatively robust homogeneous catalysts

✍ Scribed by Eduardo Peris; Robert H Crabtree


Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
136 KB
Volume
6
Category
Article
ISSN
1631-0748

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The titanocene complex shown in the scheme, which is generated by an asymmetric thermal transformation of the corresponding binaphthol complex and subsequent chlorination, is found to be an efficient catalyst for the hydrogenation of cyclic and noncyclic imines. -