✦ LIBER ✦
ChemInform Abstract: ansa-Metallocene Derivatives. Part 44. Asymmetric Thermal Transformation, a New Way to Enantiopure Biphenyl-Bridged Titanocene and Zirconocene Complexes: Efficient Catalysts for Asymmetric Imine Hydrogenation.
✍ Scribed by Markus Ringwald; Rainer Stuermer; Hans H. Brintzinger
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
✦ Synopsis
The titanocene complex shown in the scheme, which is generated by an asymmetric thermal transformation of the corresponding binaphthol complex and subsequent chlorination, is found to be an efficient catalyst for the hydrogenation of cyclic and noncyclic imines.