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New route to the preparation and configurational correlation of optically active phosphine oxides

✍ Scribed by Korpiun, Olaf.; Mislow, Kurt.

Book ID
120504388
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
389 KB
Volume
89
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Stereospecific reduction of diastereomer
Stereospecific reduction of diastereomerically pure menthyl phosphinates: a new route to optically active phosphine oxides
✍ Yasuhiro Koide; Atsushi Sakamoto; Tsuneo Imamoto πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 French βš– 140 KB

Diastereomerically pure menthyl phosphinates are stereospecifically reduced by lithium 4,4'-di-fertbutylbiphenylide. Subsequent treatment with alkyl halides affords phosphine oxides with high optical purity.