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New Route to the 5,12-Dihydro-7H-benzo[2,3-]azepino[4,5-b]indol-6-one Core via a Tin-Mediated Indole Synthesis.

✍ Scribed by Nicolas Henry; Jerome Blu; Valerie Beneteau; Jean-Yves Merour


Publisher
John Wiley and Sons
Year
2007
Weight
26 KB
Volume
38
Category
Article
ISSN
0931-7597

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Synthese von 7,12-Dihydro-indolo[3,2-d][
✍ Conrad Kunick πŸ“‚ Article πŸ“… 1992 πŸ› John Wiley and Sons 🌐 English βš– 224 KB πŸ‘ 1 views

## Synthesis of 7,12-Dihydro-indo~o[3~[l]benzazepin-6-(~~nes and gll-Dihydr~.thieno-[3'3':~]~zepino[qS-b]indol-5(4H)-one The title compounds 4 and 6 were prepared by Fischer indole synthesis. 4a is substituted in 10-position by reaction with bromine in glacial acetic acid. A fast ring inversion is