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New route to branched-chain sugars. Photoamidation and photohydroxyalkylation of 3-deoxy-1,2:5,6-di-O-isopropylidene-.alpha.-D-erythro-hex-3-enofuranose

✍ Scribed by Rosenthal, Alex.; Shudo, Koichi.


Book ID
120432704
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
704 KB
Volume
37
Category
Article
ISSN
0022-3263

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✍ Usama A.R. Al-Timari; LΜ†ubor FisΜ†era; Igor Goljer; Peter Ertl πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 540 KB

The synthesis of 2-phenyl-3-aryl and 2-phenyl-3-aroyl derivatives 5-(1,2-O-isopropylidene-alpha-D-xylo-tetrofuranos-4-yl)isoxazolidi ne (3) from nitrones and 5,6-dideoxy-1,2-O-isopropylidene-alpha-D-xylo-hex-5- enofuranose (1) is described. The 1,3-dipolar cycloaddition reactions given mainly anti a