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Cycloaddition of Cyclopentadiene to 3-Deoxy-1,2:5,6-di- O -isopropylidene-α- d - erythro -hex-3-enofuranose. Synthesis and Representative Chemistry of 1,6-Anhydro-2,3-dideoxy-β- d - glycero -hex-2-enopyran-4-ulose (“Isolevoglucosenone”)

✍ Scribed by Horton, Derek; Roski, James P.; Norris, Peter


Book ID
121331652
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
358 KB
Volume
61
Category
Article
ISSN
0022-3263

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Replacement of natural sugars by 4-deoxy-D-lyxo-hexose ("4-deoxy-D-mannose", 8) as the component parts of saccharides may endow compounds with new functions or biological activities. In previous studies, syntheses of 8 gave low overall yields or required many steps 1-4 Thus a simplified synthetic ro