New ring systems derived from 4,5-diaminobenzo[b]thiophen and its 3-methyl derivative
โ Scribed by Chapman, N. B.; Clarke, K.; Sharma, K. S.
- Book ID
- 121383538
- Publisher
- The Royal Society of Chemistry
- Year
- 1971
- Tongue
- English
- Weight
- 494 KB
- Category
- Article
- ISSN
- 0022-4952
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract The synthesis of the previously unknown parent ring system was developed. Treatment of 3โhydrazinoโ1,2,4,5โtetrazine (4) with diethoxymethyl acetate gave the parent ring system. Similar treatment of 3โ(3,5โdimethylpyrazolโ1โyl)โ6โhydrazinoโ1,2,4,5โtetrazine (2) with one carbon cyclizing
## Abstract magnified image The reaction of potassium cyanoacetohydroxamate **1** with ethyl 2โarylโhydrazonoโ3โoxobutyrates **2** gave the unexpected pyrazolo[3,4โ__c__]pyridazines **7** and isoxazolo[5,4โ__b__]pyridines **10** __via__ a oneโpot reaction. A mechanistic proof is suggested to accou