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NEW REARRANGEMENTS OF THE CARYOPHYLLENE SKELETON: THE DINITROPHENYLHYDRAZONES FROM CARYOPHYLLENE OXIDE

✍ Scribed by Warnhoff, E. W.

Book ID
124102719
Publisher
NRC Research Press
Year
1964
Tongue
French
Weight
557 KB
Volume
42
Category
Article
ISSN
0008-4042

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πŸ“œ SIMILAR VOLUMES

A novel radical induced rearrangement of
A novel radical induced rearrangement of the caryophyllene skeleton
✍ L.M. van der Linde; A.J.A. van der Weerdt πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 French βš– 188 KB

The addition of an acetyl radical on caryophyllene leads to formation of the four isomeric ketones 5-8 involving a novel rearrangement of the caryophyllene skeleton. The acid catalyzed rearrangement of caryophyllene 1 has been studied in detail'. The final re-\_ action products are clovene 2, caryo