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New reaction of cyclic nitronates: C,C-cross coupling with silyl enolates

โœ Scribed by Vladimir O. Smirnov; Alexander A. Tishkov; Sema L. Ioffe; Georgy V. Zatonsky; Yurii A. Strelenko; William A. Smit


Book ID
111730329
Publisher
Royal Society of Chemistry
Year
2002
Tongue
English
Weight
91 KB
Volume
12
Category
Article
ISSN
0959-9436

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## Abstract Nitronate anions derived from primary and secondary nitroalโ€kanes undergo crossโ€coupling reactions with diethyl alkylmalonate anions in alcohol/DMF solution when treated with silver nitrate. A catalytic amount of chloride ions is necessary to promote selective reaction.