New process for the preparation of M2+?V2O5?H2O xerogels and their transformation to ?-M2+?V2O5 bronzes (M ? Ca, Mn, Co, Ni, Cu)
β Scribed by Watanabe, T.; Shimizu, A.; Inagaki, M.
- Book ID
- 121466493
- Publisher
- Royal Society of Chemistry
- Year
- 1995
- Tongue
- English
- Weight
- 452 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0959-9428
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Single crystals of hydrated vanadium oxides with layered structures containing divalent Ca or Ni were hydrothermally grown, and their structural characterization was focused on the interlayer sites. Both compounds are formulated by M 0.25 V 2 O 5 β’ H 2 O, M β«Ψβ¬ Ca, Ni and crystallize in the monoclin
New -type layered vanadium bronzes M 0.25 V 2 O 5 β’ H 2 O were hydrothermally synthesized for divalent metals of M β«Ψβ¬ Mg, Co, Ni in addition to the first-reported M β«Ψβ¬ Zn compound. The -type structures, consisting of V 2 O 5 layers with three octahedral and one tetrahedral V atoms and interlayer M