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The Dimeric [V2O4F6]4– Vanadium Oxide-Fluoride Anion in Na2(M(H2O)2)(V2O4F6) (M = Co2+, Ni2+, and Cu2+)

✍ Scribed by Martin D. Donakowski; Anastasiya I. Vinokur; Prof. Dr. Kenneth R. Poeppelmeier


Book ID
112233522
Publisher
John Wiley and Sons
Year
2012
Tongue
German
Weight
337 KB
Volume
638
Category
Article
ISSN
0372-7874

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[H2en]2{La2M(SO4)6(H2O)2} (M=Co, Ni): Fi
✍ Yan-Ping Yuan; Rui-Yao Wang; De-Yuan Kong; Jiang-Gao Mao; Abraham Clearfield 📂 Article 📅 2005 🏛 Elsevier Science 🌐 English ⚖ 407 KB

The first organically templated 3d-4f mixed metal sulfates, [H 2 en] 2 {La 2 M(SO 4 ) 6 (H 2 O) 2 } (M ¼ Co 1, Ni 2) have been synthesized and structurally determined from non-merohedrally twinned crystals. The two compounds are isostructural and their structures feature a three-dimensional anionic