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New Perspectives on the Nucleophilic Addition Step in the Wacker Process

✍ Scribed by Siegbahn, Per E. M.


Book ID
127144693
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
841 KB
Volume
117
Category
Article
ISSN
0002-7863

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The Wacker Process: Inner- or Outer-Sphe
✍ Aleix Comas-Vives; AndrΓ‘s Stirling; AgustΓ­ LledΓ³s; Gregori Ujaque πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 492 KB

The Wacker process consists of the oxidation of ethylene catalyzed by a Pd(II) complex. The reaction mechanism has been largely debated in the literature; two modes for the nucleophilic addition of water to a Pd-coordinated alkene have been proposed: syn-inner- and anti-outer-sphere mechanisms. Thes