New Perfluoroalkylated BINAP Usable as a Ligand in Homogeneous and Supercritical Carbon Dioxide Asymmetric Hydrogenation.

Application of a new amidophosphite liga

Application of a new amidophosphite ligand to Rh-catalyzed asymmetric hydrogenation of β-dehydroamino acid derivatives in supercritical carbon dioxide: Activation effect of protic co-solvents

✍ Sergey E. Lyubimov; Eugenie A. Rastorguev; Vadim A. Davankov 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 95 KB

## Abstract New chiral amidophosphite ligand was synthesized and tested in the Rh‐catalyzed asymmetric hydrogenation of (__Z__)‐β‐(acylamino)acrylates in protic solvents and supercritical carbon dioxide (scCO~2~) The catalytic performance is affected greatly by the acidity of the solvents. Better e