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New Paradigms for Organic Catalysts: The First Organocatalytic Living Polymerization

✍ Scribed by Fredrik Nederberg; Eric F. Connor; Michael Möller; Thierry Glauser; James L. Hedrick


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
88 KB
Volume
113
Category
Article
ISSN
0044-8249

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New Paradigms for Organic Catalysts: The
✍ Fredrik Nederberg; Eric F. Connor; Michael Möller; Thierry Glauser; James L. Hed 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 98 KB 👁 1 views

A metal-free approach to the living ring-opening polymerization (ROP, shown schematically) of lactide has been developed using strongly basic amines such as 4-(dimethylamino)pyridine as transesterification catalysts. These organic catalysts must be used in combination with a nucleophile such as an a