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New Organosilyl Derivatives of the Dawson Polyoxometalate [α2-P2W17O61(RSi)2O]6−: Synthesis and Mass Spectrometric Investigation

✍ Scribed by Cédric R Mayer; Catherine Roch-Marchal; Hélène Lavanant; René Thouvenot; Nicole Sellier; Jean-Claude Blais; Francis Sécheresse


Book ID
101834707
Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
287 KB
Volume
10
Category
Article
ISSN
0947-6539

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✍ Marie-Anne Pilette; Sébastien Floquet; Jérôme Marrot; Emmanuel Cadot 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 567 KB

The [(P 4 W 34 O 61 ) 2 {Mo 4 S 4 O 4 (OH 2 ) 2 }] 16-anion was obtained by the stereospecific addition of the [Mo 2 S 2 O 2 ] 2+ oxothio cation to the monovacant α 2 -[P 2 W 17 O 61 ] 10-anion. The mixed salt K 9 Na 7 [(P 2 W 17 O 61 ) 2 {Mo 4 S 4 O 4 (OH 2 ) 2 }]•50H 2 O was isolated as single cry