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Preparation, electrochemistry and crystal structure of a derivative of 18-tungstophosphate with Dawson structure: K16H[Yb(α-2-P2W17O61)2]·44H2O

✍ Scribed by Jingyang Niu; Junwei Zhao; Dongjie Guo; Jingping Wang


Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
276 KB
Volume
692
Category
Article
ISSN
0022-2860

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The [(P 4 W 34 O 61 ) 2 {Mo 4 S 4 O 4 (OH 2 ) 2 }] 16-anion was obtained by the stereospecific addition of the [Mo 2 S 2 O 2 ] 2+ oxothio cation to the monovacant α 2 -[P 2 W 17 O 61 ] 10-anion. The mixed salt K 9 Na 7 [(P 2 W 17 O 61 ) 2 {Mo 4 S 4 O 4 (OH 2 ) 2 }]•50H 2 O was isolated as single cry