A new mixed-valent vanadium tungsten monophosphate Cs 5 V 2 W 4 O 13 (PO 4 ) 4 has been synthesized in air in spite of the presence of V(IV). It crystallizes in the space group Cmc2 1 with a โซุโฌ 14.948(1), b โซุโฌ 20.008(2), and c โซุโฌ 9.942(1) A s . Its original structure, built up from W 2 O 11 bioct
New mixed valent vanadium monophosphate with an intersecting tunnel structure Ba2V5O8(PO4)4
โ Scribed by Borel, M. M.; Leclaire, A.; Chardon, J.; Raveau, B.
- Book ID
- 125815005
- Publisher
- Royal Society of Chemistry
- Year
- 1998
- Tongue
- English
- Weight
- 185 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0959-9428
- DOI
- 10.1039/A706529I
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
New mixed valent monophosphates \(A_{3} \mathrm{O}_{2}\left(\mathrm{MoO}_{4}\right)_{4}\left(\mathrm{PO}_{4}\right)_{4}\) with an intersecting tunnel structure have been isolated for \(A=\mathrm{Rb}, \mathrm{Tl}\). The structure of the \(\mathrm{Rb}-\) phase has been solved from a single crystal X-r
A vanadium (V) monophosphate, KV 2 O 4 PO 4 , with an original tunnel structure has been synthesized. It crystallizes in the space group Pn2 1 a, with a โซุโฌ 13.924(1) A s s , b โซุโฌ 19.946(1) A s s , c โซุโฌ 4.749(1) A s s . The [V 2 PO 8 ] framework consists of 903 3 oriented [V 2 O 8 ] pyramidal chai