A New Mixed Valent Molybdenum Monophosphate with a Tunnel Structure: LixMo2O3(PO4)2
โ Scribed by S. Ledain; A. Leclaire; M.M. Borel; B. Raveau
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 338 KB
- Volume
- 122
- Category
- Article
- ISSN
- 0022-4596
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๐ SIMILAR VOLUMES
New mixed valent monophosphates \(A_{3} \mathrm{O}_{2}\left(\mathrm{MoO}_{4}\right)_{4}\left(\mathrm{PO}_{4}\right)_{4}\) with an intersecting tunnel structure have been isolated for \(A=\mathrm{Rb}, \mathrm{Tl}\). The structure of the \(\mathrm{Rb}-\) phase has been solved from a single crystal X-r
A new mixed-valent molybdenum monophosphate \(\mathrm{Cs}_{6} \mathrm{Mo}_{7} \mathrm{O}_{9}\left(\mathrm{PO}_{4}\right)_{7} \cdot \mathrm{H}_{2} \mathrm{O}\) has been isolated by solid state chemistry. It crystallizes in the space group Pnma with \(a=10.084(1) \AA\), \(b=21.297(3) \AA\), \(c=17.491
A new mixed-valent molybdenum monophosphate with a layer structure \(\mathrm{KMo}_{3} \mathrm{P}_{2} \mathrm{O}_{14}\) has been isolated. It crystallizes in the space group \(P 2_{l} / m\) with \(a=8.599\) (2) \(\AA, b=6.392\) (2) \(\AA, c=10.602\) (1) \(\AA\), and \(\beta=111.65(2)^{\circ}\). The l