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New Method for the General Synthesis of [1,2,4]Triazolo[1,5-a]pyridines

โœ Scribed by Elliott Huntsman; Jaume Balsells


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
93 KB
Volume
2005
Category
Article
ISSN
1434-193X

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The 1-substituted ethylidenemalononitriles la-c condensed with triethyl orthoformate in refluxing acetic anhydride to yield the dienes 2a-c. On the other hand, a mixture o f N, N-dimethylformamide and triethyl orthoformate condensed with la-d to yield the N, N-dimethylaminopentadienonitriles 2d-g. T

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Synthese von 2H-1,2,3-Triazolo[4,5-~][1,2,4]triazolo[4,3-a]pyridinen und verwandten Systemen Zur Herstellung des 2H-1,2,3-Triazolo[4,5-c]pyridin-4(5H)-ons 4 wurde 2-Phenyl-2H-l,2,3triazol-4-carbaldehyd (1) zunichst in die Acrylsiiure 2 umgewandelt und letztere dann nach vorausgehender Curtius-Umlage