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New Mechanistic Aspects on the Catalytic Transformation of Vinylthiiranes to Mono and Disubstituted 3,6-Dihydro-1,2-dithiins by Tungsten Pentacarbonyl Monoacetonitrile.

✍ Scribed by David W. Lupton; Dennis K. Taylor

Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 33
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200241151

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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ChemInform Abstract: Catalytic Transform

ChemInform Abstract: Catalytic Transformations of Vinylthiiranes by Tungsten Carbonyl Complexes. A New Route to 3,6-Dihydro-1,2-dithiins.

✍ Richard D. Adams; Joseph L. Perrin 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 2 views

Catalytic Transformations of Vinylthiiranes by Tungsten Carbonyl Complexes. A New Route to 3,6-Dihydro-1,2-dithiins. -Two equivalents of vinylthiiranes (I) are transformed in the presence of W(CO) 5 (MeCN) catalyst to dithiins (II) and butadiene in good yields. Complexes W(CO) 4 (PPhR 2 )(MeCN) (R