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New lanthanide(III) complexes of chiral nonadendate macrocyclic amine derived from (1R,2R)-1,2-diaminocyclohexane and 2,6-diformyl-4-methylphenol

✍ Scribed by Marta Paluch; Jerzy Lisowski


Book ID
116602437
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
289 KB
Volume
451
Category
Article
ISSN
0925-8388

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New chiral amino-phosphoramidite and bis
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New bidentate amino-phosphoroamidite and diphosphoroamidite ligands derived from inexpensive (R,R)-1,2diaminocyclohexane have been synthesized and screened in the Cu-catalyzed asymmetric conjugate addition of Et 2 Zn to 2-cyclohexenone. The highest 74% ee value was reached with the N,N%-dimethyl sub