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Enantiopure Chiral Macrocyclic Lanthanide Complexes Derived from (R)-2,2′-Diamino-1,1′-binaphthyl and 2,6-Diformylpyridine

✍ Scribed by Jerzy Lisowski; Marta Paluch; Tadeusz Lis

Book ID
106388687
Publisher
Springer Netherlands
Year
2006
Tongue
English
Weight
315 KB
Volume
55
Category
Article
ISSN
0923-0750

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## Abstract Reaction of (__R__)‐bis(pyrrol‐2‐ylmethyleneamino)‐1,1′‐binaphthyl (1H~2~) or (__R__)‐__N__,__N′__‐bis(pyridin‐2‐ylmethyl)‐1,1′‐binaphthyl‐2,2′‐diamine (2H~2~) with Zr(NMe~2~)~4~ (1 equiv.) gives chiral zirconium amides 1‐Zr(NMe~2~)~2~·C~7~H~8~ (4·C~7~H~8~) or 2‐Zr(NMe~2~)~2~ (6) in goo