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New Intermediate Steps in the Synthesis of Larger Nickel Clusters

✍ Scribed by Prof. Dr. Dieter Fenske; Dr. Harald Krautscheid; Dipl.-Chem. Michael Müller

Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
473 KB
Volume
31
Category
Article
ISSN
0044-8249

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✦ Synopsis

Phosphane complexes of NiCl~2~ react with Se(SiMe~3~)~2~ affording mixtures of cluster complexes whose structures are dependent on the phosphane ligands. Through the variation of the ligands, complexes 1–6 were isolated and structurally characterized (Phe = C~2~H~4~Ph). Cluster 2 incorporates a spirocyclic Ni~5~ framework, 6 a central Ni~13~ cuboctahedron.
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