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New Insights on the Mechanism of the Transition-Metal Stereoselective Olefin Cyclopropanation

✍ Scribed by Elena Soriano; José Marco-Contelles

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
563 KB
Volume
14
Category
Article
ISSN
0947-6539

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The mechanism of copper(I)-catalyzed olefin cyclopropanation with diazomethanes has been studied at the BP86/AE1 level of density-functional theory. For the model system Cu(diazabutadiene) + + ethene + diazomethane, copper carbene complexes are confirmed as viable intermediates, with rate-determinin