The mechanism of copper(I)-catalyzed olefin cyclopropanation with diazomethanes has been studied at the BP86/AE1 level of density-functional theory. For the model system Cu(diazabutadiene) + + ethene + diazomethane, copper carbene complexes are confirmed as viable intermediates, with rate-determinin
✦ LIBER ✦
Density Functional Study of Possible Intermediates in the Mechanism of Olefin Cyclopropanation Catalyzed by Metal Carboxylates
✍ Scribed by Cristóbal Rodríguez-García; Òscar González-Blanco; Antonio Oliva; Rosa M. Ortuño; Vicenç Branchadell
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 403 KB
- Volume
- 2000
- Category
- Article
- ISSN
- 1434-1948
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✦ Synopsis
Density Functional Study of Possible Intermediates in the Mechanism of Olefin Cyclopropanation Catalyzed by Metal Carboxylates
Cristo ´bal Rodrı ´guez-
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