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New highly regioselective reactions of unprotected sucrose. Synthesis of 2-O-acylsucroses and 2-O-(N-alkylcarbamoyl)sucroses

✍ Scribed by Chauvin, Caroline; Baczko, Krystyna; Plusquellec, Daniel


Book ID
120982906
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
638 KB
Volume
58
Category
Article
ISSN
0022-3263

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Synthesis of 4-O- and 6-O-monoacryloyl d
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The synthesis of an ethylenic orthoester of sucrose by transorthoesterification of an acrylic reagent with sucrose is described. Mild hydrolysis of this orthoester gave sucrose selectively monosubstituted by an acryloyl group at either the 4-O-or the 6-O-position. These acrylates were homopolymerize