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Synthesis of 6-O-acetyl-2,3,4-tri-O-[(S)-2-methylbutyryl]sucrose and the three regioisomers of 6-O-acetyl-2,3,4-O-[(S)-2-methylbutyryl]-di-O-[(S)-3-methylpentanoyl]sucrose, naturally occurring fatty acid esters of sucrose found in tobacco

✍ Scribed by Stefan Oscarson; Helena Ritzén


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
340 KB
Volume
284
Category
Article
ISSN
0008-6215

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✍ Thomas Richter; Peter Luger; Tadashi Hanaya; Hiroshi Yamamoto 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 780 KB

X-ray crystallographic analyses are reported for the two title compounds (8 and 9), of which the former crystallized in two modifications (8n and 8b). In all three structures, the pyranose rings have the %, (D) conformation and the substituents at C-l are axial and those at C-24-4 are equatorial. Th