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New furoxan chemistry. 2. Chemistry of acyl nitrile oxides generated in situ by thermolysis of diacylfuroxans

✍ Scribed by Brittelli, David R.; Boswell, George A.


Book ID
118747326
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
621 KB
Volume
46
Category
Article
ISSN
0022-3263

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New method of in situ generation of nitr
✍ JarosΕ‚aw Kiegiel; Magdalena PopΕ‚awska; Julita JΓ³ΕΊwik; MaΕ‚gorzata Kosior; Janusz πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 197 KB

Manganese(IV) oxide (MnO~\_) was found to oxidize aldoximes to nitrile oxides. Nitrile oxides were trapped in situ with dipolarophiles to furnish 2-oxazolines, The best results were obtained with hydroximinoacetates as nitrile oxide precursors.