๐”– Bobbio Scriptorium
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New fluorine-containing building blocks from trifluoroethanol. 2.

โœ Scribed by Judith A. Howarth; W. Martin Owton; Jonathan M. Percy; Michael H. Rock

Book ID
103399610
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
926 KB
Volume
51
Category
Article
ISSN
0040-4020

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2,2,2-Trifluoroacetimidoyl chlorides 1 are much more stable than the corresponding nonfluorinated chlorides because of the deactivation for hydrolysis by the strong electronwithdrawing fluorine atom and thus useful as synthetic blocks. They react smoothly with nucleophilics such as Grignard reagent