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New Enantioselective Synthesis of (10R,11S)-(+)-Juvenile Hormones I and II

✍ Scribed by Tomoko Okochi; Kenji Mori


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
314 KB
Volume
2001
Category
Article
ISSN
1434-193X

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## Abstract Radiolabeled optically‐active JH III bisepoxide ([^3^H]‐(10__R__)‐JHB~3~) was synthesized from [12‐^3^H] (10__R__)‐JH III using dimethyldioxirane to give an inseparable mixture of diastereomers with the __trans__‐6,7‐epoxide __syn__ or __anti__ to the existing 10,11‐epoxide. [^3^H]‐(10_