The laser ablation with prompt reaction and detection method was employed to provide a survey of some gasphase reactions of actinide (M = U, Np, Pu and Am) and lanthanide (M = Tb and Tm) ions, M Y and MO 1,2 Y , with alcohols, thiols and ethers. Particular attention was given the changing behavior i
New developments in gas-phase actinide ion chemistry
✍ Scribed by John K. Gibson; Joaquim Marçalo
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 191 KB
- Volume
- 250
- Category
- Article
- ISSN
- 0010-8545
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✦ Synopsis
In this review, recent progress in the study of the chemistry of actinide ions in the gas phase is summarized. The new results, obtained using various mass spectrometric techniques, encompass reactivity studies of bare and ligated actinide ions with inorganic and organic molecules, thermochemical studies of neutral and ionic actinide oxides, and solvation studies of ionic actinide species. A few examples of the implications of this fundamental research to other aspects of actinide chemistry are presented. Potential future work in this area is briefly discussed.
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