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New degradable polyethers based on the tautomerism of pyrimidine bases in the main chain

✍ Scribed by Seiji Sasaki; Koichi Kondo

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
205 KB
Volume
38
Category
Article
ISSN
0887-624X

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✦ Synopsis

The tautomerism of pyrimidine bases was applied to a new type of polymer synthesis that was achieved by the dehydrochlorination of dichloropyrimidines with diols to give polyethers containing a 2,4-pyrimidine structure in the main chain. The polymer decomposed to uracil or thymine under an acidic condition but not under a basic condition. A degradation based on tautomerism could be useful for a new kind of degradable polymer synthesis and polymer drug-delivery system.

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