✦ LIBER ✦
Molybdenum tetracarbonyl complexes with linear chain polyether-containing Schiff base ligands and their reactivity in the polymerization of methyl methacrylate
✍ Scribed by Ayfer Menteş; Mithat Sarbay; Baki Hazer; Hülya Arslan
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 112 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0268-2605
- DOI
- 10.1002/aoc.835
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✦ Synopsis
Mo(CO) 6 was reacted with the Schiff base ligand obtained by condensation reaction of 2-acetyl-or benzoylpyridine with poly(propylene glycol)bis(2-aminopropyl ether) to obtain polymeric, dinuclear metal tetracarbonyl compounds. The long-chain Schiff base complexes are highly soluble even in non-polar solvents such as petroleum ether, diethyl ether and n-hexane. These complexes, as freeradical initiators, afforded methyl methacrylate polymerization in chlorinated solvents.