Base-catalyzed reaction of 5-acylmethyl-2,5-di-t-butyl-4-oxa-2-cyclopentenones selectively derived from 4-alkyl-2,6-di-t-butylphenols via three steps involving oxygenation, acetylation, and acid-treatment gave 3-alkyl-2,5-di-t-butyl-2,4-cyclopentadienones in excellent yield. Previously, we have repo
New Compounds. 4- n -Butyl-2, 6-di- t -butylphenol
โ Scribed by Yohe, G R.; Blodgett, Eva O.; Loranger, Wm F.
- Book ID
- 127305458
- Publisher
- American Chemical Society
- Year
- 1949
- Tongue
- English
- Weight
- 120 KB
- Volume
- 71
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
The oxygenation of 4-(N-arylmethyleneamino)-2,6-di-t-butylphenols with Co(Salpr), a five coordinate Co(I1) Schiff base complex, in CH2C12 results in the regioselective hydroperoxylation at the imino carbon to give N-(1-aryl-1-hydroperoxymethyl)-3,5-di-tbutyl-R-benzoquinone mnoimines, which give excl
In a previous paper,' we reported a novel base-catalyzed rearrangement of R-peroxyquinol esters derived from 2,6-di-t-butylphenols leading to quinoxyacetic acid derivatives, where the peroxy bond cleaves even below -60 "C. Nature of the peroxy bond cleavage has been remained n