New chiral Schiff base–zinc complexes and their esterolytic catalytic activity
✍ Scribed by Ramu Kannappan; Masaomi Matsumoto; John Hallren; Kenneth M. Nicholas
- Publisher
- Elsevier Science
- Year
- 2011
- Tongue
- English
- Weight
- 391 KB
- Volume
- 339
- Category
- Article
- ISSN
- 1381-1169
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## Abstract A series of enolic Schiff base aluminum(III) complexes LAlR (where L=NNOO‐tetradentate enolic Schiff base ligand) containing ligands that differ in their steric and electronic properties were synthesized. Their single crystals showed that these complexes are five‐coordinated around the
The aldimines FcCH=NCH(Me)CH 2 OMe (1), FcCH=NCH 2 H 6 H 4 -2-OMe (2) and FcCH=N(CH 2 ) 3 NHMe (3) were obtained by reacting ferrocene aldehyde with the corresponding primary amines. Compounds 1±3 react with Me 2 Zn and Me 3 Al in a molar ratio 1 : 1 to the corresponding adducts 4±8. Reactions of 1