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Synthesis of Schiff Base-Ruthenium Complexes and Their Applications in Catalytic Processes

✍ Scribed by Renata Drozdzak; Bart Allaert; Nele Ledoux; Ileana Dragutan; Valerian Dragutan; Francis Verpoort


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
382 KB
Volume
347
Category
Article
ISSN
1615-4150

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The reaction of the Schiff bases (obtained by condensing isatin with o-aminophenol/o-aminothiophenol/o-aminobenzoic acid) with [RuX 3 (EPh 3 ) 3 ] (where X = Cl/Br; E = P/As) in benzene afforded new, air-stable Ru(III) complexes of the general formula [Ru(L)X(EPh 3 ) 2 ] (L = dianion of tridentate S

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## Abstract The synthesis and characterization of several hexa‐coordinated ruthenium(III) complexes of the type [RuCl(PPh~3~)~2~(L)] (L = dibasic tridentate ligand derived by the condensation of salicylaldehyde/__o__‐vanillin with __o__‐aminophenol/__o__‐aminothiophenol) are reported. IR, electroni