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New chiral Schiff bases derived from (+)- and (−)-α-pinenes in the metal complex catalyzed asymmetric oxidation of sulfides

✍ Scribed by E. A. Koneva; K. P. Volcho; D. V. Korchagina; N. I. Komarova; A. I. Kochnev; N. F. Salakhutdinov; A. G. Tolstikov


Publisher
Springer
Year
2008
Tongue
English
Weight
395 KB
Volume
57
Category
Article
ISSN
1573-9171

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Double asymmetric synthesis: Palladium c
✍ J.P. Genet; N. Kopola; S. Juge; J. Ruiz-Montes; O.A.C. Antunes; S. Tanier 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 270 KB

A new double asymmetric induction in carbon-carbon bond formation is -achieved by the use of palladium chiral complexes in the alkylation of chiral Schiff bases1 derived from glycine. High diastereoisomeric excesses are obtained (90-999) using N.N-cyclohexylsulfamoylisobornyl derivatives and DIOP as