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New chiral N-(N,N-dialkylamino)sulfamoyl-1,2-diamine ligands for highly enantioselective transfer hydrogenation of ketones

✍ Scribed by Damjan Šterk; Massoud S. Stephan; Barbara Mohar


Book ID
104359497
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
105 KB
Volume
13
Category
Article
ISSN
0957-4166

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N,N′-Dialkylated 1,2-diamine derivatives
✍ Geon-Joong Kim; Sang-Han Kim; Pong-Hyun Chong; Mi-Ae Kwon 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 110 KB

Chiral N,N%-dialkylated cyclohexanediamine derivatives ligands have been synthesized and used in an asymmetric transfer hydrogenation of aryl ketones. Optically active alcohols with up to 93% enantiomeric excess were obtained in high yield.