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New Chiral Hypervalent Iodine Compounds in Asymmetric Synthesis

✍ Scribed by Hirt, Urs H.; Spingler, Bernhard; Wirth, Thomas

Book ID
120420782
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
89 KB
Volume
63
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

Chiral hypervalent iodine compounds
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✍ Thomas Wirth; Urs H. Hirt πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 English βš– 256 KB

The synthesis of non-racemic chiral hypervalent iodine reagents is described together with the first application of these reagents in asymmetric functionalizations of ketones and alkenes. Q 1997, Elsevier

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A series of ortho-substituted chiral hypervalent iodine reagents has been synthesized utilizing a zirconium-mediated iodoacylation reaction, which was followed by a stereoselective reduction, methylation, and an oxidation/ligand-exchange sequence. The evaluation of these new compounds as stereoselec