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Chiral hypervalent iodine compounds

✍ Scribed by Thomas Wirth; Urs H. Hirt

Book ID
104360927
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
256 KB
Volume
8
Category
Article
ISSN
0957-4166

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✦ Synopsis

The synthesis of non-racemic chiral hypervalent iodine reagents is described together with the first application of these reagents in asymmetric functionalizations of ketones and alkenes. Q 1997, Elsevier

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Chiral Hypervalent Organo-Iodine(III) Co
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✍ UrsΒ H. Hirt; MartinΒ F.Β H. Schuster; AndrewΒ N. French; OlafΒ G. Wiest; Thomas Wirt πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 431 KB πŸ‘ 2 views

A series of ortho-substituted chiral hypervalent iodine reagents has been synthesized utilizing a zirconium-mediated iodoacylation reaction, which was followed by a stereoselective reduction, methylation, and an oxidation/ligand-exchange sequence. The evaluation of these new compounds as stereoselec